Bis[μ-bis-(diphenyl-phosphino)methane-κP:P']bis-[(chloro-difluoro-acetato-κO)silver(I)](Ag-Ag).

K.M. Lo
S.W. Ng

Document Type

Article

Publication Date

1-1-2008

Abstract

The asymmetric unit of the title compound, [Ag(2)(C(2)ClF(2)O(2))(2)(C(25)H(22)P(2))(2)], consists of two half-mol-ecules, each Ag(I) ion lying on a center of symmetry. In each complete mol-ecule, two bis-(diphenyl-phosphino)methane ligands bridge two Ag(I) ions, which are further coordinated by one chloro-difluoro-acetate ligand, giving T-shaped geometries and short intra-molecular Ag⋯Ag distances of 3.1078 (6) and 2.9950 (6) Å. In one mol-ecule, the unique -CF(2)Cl group is rotationally disordered over two sites with approximate occupancies of 0.53 and 0.47 for the major and minor components, respectively.

Keywords

Chemistry

Divisions

CHEMISTRY

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

64

Issue

Pt 5

Publisher

International Union of Crystallography

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