Bis[1,2-bis-(diphenyl-phosphino)ethane-κP:P']silver(I) bis-(chloro-difluoro-acetato-κO)(4-chloro-phen-yl)diphenyl-stannate(IV).

Document Type

Article

Publication Date

1-1-2008

Abstract

In the title salt, [Ag(C(26)H(24)P(2))(2)][Sn(C(2)ClF(2)O(2))(2)(C(6)H(5))(2)(C(6)H(4)Cl)], the Ag(I) atom has a tetra-hedral and the Sn(IV) atom a trans-trigonal-bipyramidal coordination geometry. In the anion, the chloro substituent is disordered over two rings (occupancy ratio 0.81:0.19); the two chloro-difluoro-methyl groups are also disordered over two sites for their halogen atoms (occupancy ratios 0.72:0.28 and 0.70:0.30).

Keywords

Chemistry

Divisions

CHEMISTRY

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

64

Issue

Pt 6

Publisher

International Union of Crystallography

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