Document Type
Article
Publication Date
1-1-2010
Abstract
All non-H atoms of the title compound, C(6)H(7)N(3)OS, which exists in the thione form, lie in a common plane (r.m.s. of non-H atoms = 0.08 angstrom). The amino group of the -NH-NH(2) substituent forms an intramolecular hydrogen bond to the S atom. The terminal -NH(2) group is pyramidally coordinated; it forms a weak N-H center dot center dot center dot O and a weak N-H center dot center dot center dot S hydrogen bond. Furthermore, the N atom is an acceptor for a C-H center dot center dot center dot N contact. The amino group of the ring is a hydrogen-bond donor to the carbonyl O atom of an adjacent molecule, this interaction giving rise to a linear chain motif running along the b axis.
Keywords
Amino group hydrogen-bond donor adjacent molecule, Linear chain
Publication Title
Acta Crystallographica Section E: Structure Reports Online
ISSN
1600-5368
Recommended Citation
Ariffin, Azhar; Ng, S.W.; Mansor, S.; and Yehye, W.A., "2-Sulfanylidene-1,2-dihydropyridine-3-carbohydrazide" (2010). Research Publications (2006 to 2010). 4242.
https://knova.um.edu.my/research_publications_2006_2010/4242
Divisions
CHEMISTRY
Volume
66
Issue
10
Publisher
International Union of Crystallography
Additional Information
Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA