Tetra-mu-acetato-kappa O-8:O `-bis[(N-ethylpyrimidin-2-amine)copper(II)](Cu-Cu)

Document Type

Article

Publication Date

1-1-2010

Abstract

In the centrosymmetric title molecule, [Cu-2(CH3COO)(4)-(C6H9N3)(2)], each of the four acetate groups bridges a pair of Cu-II atoms [Cu-Cu = 2.6540 (4) angstrom]. The distorted octahedral geometry of the metal atom is completed by an N-donor atom of the N-ethylpyrimidin-2-amine ligand: an intramolecular N-H center dot center dot center dot O hydrogen links its N-H group to an acetate carboxylate O atom. In the crystal, C-H center dot center dot center dot O interactions link the molecules into a supramolecular chain along the b axis.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

66

Issue

9

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA

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