Poly[[tris(N,N-dimethylformamide)-(mu(4)-5-nitroisophthalato)(mu(3)- 5-nitroisophthalato)dicobalt(II)] N,N-dimethylformamide monosolvate]

Document Type

Article

Publication Date

1-1-2010

Abstract

In the polymeric title compound, [Co-2(C3H7NO)(3)(C8H3NO6)(2)]center dot C3H7NO, one 5-nitroisophthalate dianion has its two carboxylate groups chelating to one Co-II atom while simultaneously coordinating to another metal atom in a mu(4)-bridging mode. The other 5-nitroisophthalte dianion has one carboxylate group chelating to a metal atom whereas the other bridges two metal atoms in a mu(3)-bridging mode. Both metal atoms show an octahedral coordination. The polymer adopts a layer motif, with the lattice dimethylformamide molecules occupying the space between adjacent layers.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

66

Issue

10

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA

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