N `-[(2-n-Butyl-4-chloro-1H-imidazol-5-yl)methylidene]adamantane-1-carbo hydrazide sesquihydrate ethanol hemisolvate
Document Type
Article
Publication Date
1-1-2010
Abstract
In the asymmetric unit of the title compound, C(19)H(27)ClN(4)O center dot 0.5C(2)H(6)O center dot 1.5H(2)O, there are two molecules of the Schiff base, which has a rigid adamantyl cage at one end of the C(= O)NH-N=CH- chain and an almost planar [torsion angles = 1.3 (1) and 7.9 (2)degrees imidazolyl ring at the other end, three molecules of water and one molecule of ethanol. In both independent molecules of the Schiff base, this chain displays an extended zigzag configuration. All their amino groups function as hydrogen-bond donors to water molecules; these are linked to other acceptor atoms, generating a layer structure. O-H...O and O-H...N interactions involving the water molecules also occur.
Publication Title
Acta Crystallographica Section E: Structure Reports Online
Volume
66
Issue
8
Publisher
International Union of Crystallography
Publisher Location
COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA