mu-Acetato-bis(mu-2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl)amin o]methyl}phenolato)dinickel(II) chloride

Authors

• E.R.T. Tiekink
• J.L. Wardell
• C. Fernandes
• A. Horn
• J.M.S. Skakle

Document Type

Article

Publication Date

1-1-2010

Abstract

The title salt, [Ni(2)(C(16)H(18)ClN(2)O(2))(2)(CH(3)COO)]Cl, features a dinuclear cation in which the Ni atoms are triply bridged by two phenolate O ligands and a bidentate acetate ligand with all of the bridging distances essentially symmetric. Each Ni atom is also coordinated by the amine N, pyridine N and hydroxy O atoms of the 2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl) amino]methyl} phenolate ligand which is, therefore, pentadentate. The resultant N(3)O(3) donor sets define octahedral coordination geometries. The chloride counter-anion is connected to the cation via two Ohydroxy-H center dot center dot center dot Cl hydrogen bonds.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

ISSN

1600-5368

Recommended Citation

Tiekink, E.R.T.; Wardell, J.L.; Fernandes, C.; Horn, A.; and Skakle, J.M.S., "mu-Acetato-bis(mu-2-{[(3-chloro-2-hydroxypropyl)(2-pyridylmethyl)amin o]methyl}phenolato)dinickel(II) chloride" (2010). Research Publications (2006 to 2010). 3762.
https://knova.um.edu.my/research_publications_2006_2010/3762

Volume

66

Issue

5

Publisher

International Union of Crystallography