Di-n-butyl{4-hydroxy-N `-[(2-oxido-1-naphthyl-kappa O)methylene]benzohydrazidato-kappa O-2,N `}tin(IV)

Authors

• M. Abu Affan
• N. Sam
• F. Ahmad
• S.W. Ng

Document Type

Article

Publication Date

1-1-2010

Abstract

The deprotonated Schiff base ligand in the title compound, [Sn(C4H9)(2)(C18H12N2O3)],O,N,O'-chelates to the Sn atom, which is five-coordinated in a cis-C2NO2Sn trigonal-bipyramidal environment. The apical sites are occupied by the O atoms [O-Sn-O = 155.2 (2)degrees]. The hydroxy group is a hydrogen-bond donor to the two-coordinate N atom of an adjacent molecule, the hydrogen-bonding interaction giving rise to a helical chain running along the c axis. The carbon atoms of the butyl chains are equally disordered over two positions.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

ISSN

1600-5368

Recommended Citation

Abu Affan, M.; Sam, N.; Ahmad, F.; and Ng, S.W., "Di-n-butyl{4-hydroxy-N `-[(2-oxido-1-naphthyl-kappa O)methylene]benzohydrazidato-kappa O-2,N `}tin(IV)" (2010). Research Publications (2006 to 2010). 3371.
https://knova.um.edu.my/research_publications_2006_2010/3371

Volume

66

Issue

5

Publisher

International Union of Crystallography