Di-mu-azido-kappa N-4(1):N-1-bis[(1,10-phenanthroline-kappa N-2,N `)(thiocyanato-kappa N)lead(II)]

Document Type

Article

Publication Date

1-1-2010

Abstract

In the centrosymmetric binuclear title compound, [Pb-2(N-3)(2)-( NCS)(2)(C12H8N2)(4)], the N-donor atoms of one N-heterocycle and the N-donor atom of a thiocyanate anion along with the sterically active lone-pair electrons comprise an approximate square; a plane through three atoms of this square is twisted slightly with respect to the square made up of the other four atoms (two from the other N-heterocycle and one each from the bridging azide anions) at a dihedral angle of 18.7 (1)degrees. The Pb-TT atom is in a Psi-square-antiprismaic coordination.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

66

Issue

9

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA

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