Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit
Document Type
Article
Publication Date
1-1-2010
Abstract
Dimethyltin dichloride dibenzyl sulfoxide, ((CH(3))(2)SnCl(2)center dot O=S(CH(2)C(6)H(5))(2)), crystallizes in the orthorhombic space group P2(1)2(1)2(1) with a superstructure of. dimensions a = 11.9290(1), b = 19.50490(1), c = 55.7390(6) angstrom; Z = 28. The geometry of the five-coordinated tin atom in each of the seven independent adduct molecules is a square pyramid that is displaced towards a cis-trigonal bipyramid; the extent of displacement along the Berry pseudorotation pathway ranges from 20 to 45%.
Keywords
Dimethyltin dichloride-dibenzyl sulfoxide, Z ` (formula unit per asymmetric crystal unit)
Publication Title
Chinese Journal of Structural Chemistry
Recommended Citation
Ng, S.W., "Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit" (2010). Research Publications (2006 to 2010). 3367.
https://knova.um.edu.my/research_publications_2006_2010/3367
Volume
29
Issue
10
Publisher
Chinese Journal Structural Chemistry
Publisher Location
FUIJAN INST RES STRUCT MATTER, CHINESE ACAD SCIENCES, FUZHOU, FUJIAN 350002, PEOPLES R CHINA