Dimethyltin dichloride-dibenzyl sulfoxide, a compound crystallizing with seven molecules in the asymmetric unit

S.W. Ng

Document Type

Article

Publication Date

1-1-2010

Abstract

Dimethyltin dichloride dibenzyl sulfoxide, ((CH(3))(2)SnCl(2)center dot O=S(CH(2)C(6)H(5))(2)), crystallizes in the orthorhombic space group P2(1)2(1)2(1) with a superstructure of. dimensions a = 11.9290(1), b = 19.50490(1), c = 55.7390(6) angstrom; Z = 28. The geometry of the five-coordinated tin atom in each of the seven independent adduct molecules is a square pyramid that is displaced towards a cis-trigonal bipyramid; the extent of displacement along the Berry pseudorotation pathway ranges from 20 to 45%.

Keywords

Dimethyltin dichloride-dibenzyl sulfoxide, Z ` (formula unit per asymmetric crystal unit)

Publication Title

Chinese Journal of Structural Chemistry

Volume

29

Issue

10

Publisher

Chinese Journal Structural Chemistry

Publisher Location

FUIJAN INST RES STRUCT MATTER, CHINESE ACAD SCIENCES, FUZHOU, FUJIAN 350002, PEOPLES R CHINA

This document is currently not available here.

Share

COinS