Dichloridobis(1,3-phenylpropane-1,3-dionato-kappa 2 O,O')tin(IV) toluene hemisolvate

Authors

C.K. Thy
K.M. Lo
S.W. Ng

Document Type

Article

Publication Date

1-1-2010

Abstract

The two Sn-O-C-C-C-O chelate rings in the title compound, [Sn(C(15)H(11)O(2))(2)Cl(2)]center dot 0.5C(7)H(8), adopt envelope conformations, with the Sn atom deviating from the least-squares plane passing through the C and O atoms by 0.626 (1) A in one ring and by 0.690 (1) A for the other. The two planes are aligned at an angle of 59.6 (1)degrees. The Cl atoms occupy cis positions in the octahedral SnCl(2)O(4) coordination environment. The solvent molecule is disordered about a center of inversion.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

66

Issue

8

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA