Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II).

Authors

• Nurul Azimah Ikmal Hisham
• Nura Suleiman Gwaram
• Hamid Khaledi
• Hapipah Mohd AliFollow

Document Type

Article

Publication Date

1-1-2010

Abstract

In the title compound, [ZnCl(2)(C(13)H(19)N(3)O)], the Schiff base ligand acts as an N,N',N''-tridentate chelating agent, making two five-membered rings with the Zn(II) ion. The metal atom is five-coordinated by the Schiff base ligand and two Cl atoms in a distorted square-pyramidal geometry. An intra-molecular C-H⋯Cl inter-action occurs. In the crystal, adjacent mol-ecules are linked together via C-H⋯Cl hydrogen-bonding and long range C-H⋯O and C-H⋯Cl inter-actions into a three-dimensional network.

Keywords

Chemistry

Publication Title

Acta Crystallographica Section E: Structure Reports Online

ISSN

1600-5368

Recommended Citation

Ikmal Hisham, Nurul Azimah; Suleiman Gwaram, Nura; Khaledi, Hamid; and Ali, Hapipah Mohd, "Dichlorido{2-morpholino-N-[1-(2-pyrid-yl)ethyl-idene]ethanamine-κN,N',N''}zinc(II)." (2010). Research Publications (2006 to 2010). 3353.
https://knova.um.edu.my/research_publications_2006_2010/3353

Divisions

CHEMISTRY

Volume

67

Issue

Pt 1

Publisher

International Union of Crystallography

Additional Information

Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia