Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate

Authors

• N.S.A. Tajidi
• N. Abdullah
• Z. Arifin
• K.W. Tan
• S.W. Ng

Document Type

Article

Publication Date

1-1-2010

Abstract

The CuII atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)](C(6)F(5)CO(2))(2)center dot 2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetraazacyclotetradecane (cyclam) ligand and is coordinated by two water molecules in a Jahn-Teller-type tetragonally distorted octahedral geometry. The CuII atom lies on a center of inversion. The cations, anions and uncoordinated water molecules are linked by N-H...O and O-H...O hydrogen bonds, forming a layer structure parallel to (001)

Publication Title

Acta Crystallographica Section E: Structure Reports Online

ISSN

1600-5368

Recommended Citation

Tajidi, N.S.A.; Abdullah, N.; Arifin, Z.; Tan, K.W.; and Ng, S.W., "Diaqua(1,4,8,11-tetraazacyclotetradecane-kappa 4 N 1,N 4,N 8,N 11)copper(II) bis(2,3,4,5,6-pentafluorobenzoate) dihydrate" (2010). Research Publications (2006 to 2010). 3344.
https://knova.um.edu.my/research_publications_2006_2010/3344

Volume

66

Issue

8

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA