Chloridomethyl(2-methylquinolin-8-olato-kappa 2 N,O)phenyltin(IV)

Document Type

Article

Publication Date

1-1-2010

Abstract

The asymmetric unit of the title complex, [Sn(CH(3))(C(6)H(5))(C(10)H(8)NO)Cl], consists of two independent molecules, both of which have the N,O-chelated SnIV atom in a cis-C(2)SnNOCl trigonal-bipyramidal geometry [C-Sn-C = 124.82 (8) and 137.69 (8)degrees]. The Cl atom of the molecule with the smaller C-Sn-C angle interacts weakly with the SnIV atom of the molecule with the wider C-Sn-C angle at an Sn...Cl distance of 3.595 (1) A. Weak intermolecular C-H...O and C-H...Cl hydrogen bonding is present in the crystal structure.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

66

Issue

8

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA

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