catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate]

Authors

• H.D. Arman
• T. Miller
• E.R.T. Tiekink

Document Type

Article

Publication Date

1-1-2010

Abstract

The asymmetric unit of the polymeric title salt, {[Ag(C5H5-NO)(2)]PF6}(n), comprises an Ag I cation (located on a twofold axis), two 2-pyridone ligands (with distinct coordination modes), and half a PF6- anion (situated on a centre of inversion). The Ag I atom is in an approximately octahedral AgO6 coordination geometry, which is stabilized by intramolecular N-H center dot center dot center dot O hydrogen bonds. The result of the bridging mode of the 2-pyridone ligand is the formation of a supramolecular chain along the c axis; these are consolidated in the crystal by C-H center dot center dot center dot F interactions.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

ISSN

1600-5368

Recommended Citation

Arman, H.D.; Miller, T.; and Tiekink, E.R.T., "catena-Poly[[[(2-pyridone-kappa O)silver(I)]l-mu-2-pyridone-kappa O-2/O] hexafluoridophosphate]" (2010). Research Publications (2006 to 2010). 3214.
https://knova.um.edu.my/research_publications_2006_2010/3214

Volume

66

Issue

10

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA