Bis{benzyl 3-[(1H-indol-3-yl)methyl-idene]dithio-carbazato-κN,S}palladium(II) N,N-dimethyl-formamide disolvate.
Document Type
Article
Publication Date
1-1-2010
Abstract
In the title compound, [Pd(C(17)H(14)N(3)S(2))(2)]·2C(3)H(7)NO, the deprotonated Schiff base ligand acts as an N,S-bidentate chelate, forming a five-membered ring with the metal atom. The Pd(II) ion, located on an inversion center, is four-coordinated by two of the Schiff base ligands in a square-planar geometry. In the crystal, the indolic NH groups are bonded to the dimethyl-formamide (DMF) solvent mol-ecules via an N-H⋯O inter-action. In addition, C-H⋯S inter-actions are observed.
Keywords
Chemistry
Publication Title
Acta Crystallographica Section E: Structure Reports Online
ISSN
1600-5368
Recommended Citation
Khaledi, H. and Mohd A, H., "Bis{benzyl 3-[(1H-indol-3-yl)methyl-idene]dithio-carbazato-κN,S}palladium(II) N,N-dimethyl-formamide disolvate." (2010). Research Publications (2006 to 2010). 3190.
https://knova.um.edu.my/research_publications_2006_2010/3190
Divisions
CHEMISTRY
Volume
67
Issue
Pt 1
Publisher
International Union of Crystallography
Additional Information
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.