Bis[ethyl(2-hydroxyethyl)azanium] 2,2 `-disulfanediyldibenzoate
Document Type
Article
Publication Date
1-1-2010
Abstract
The asymmetric unit of the title salt, 2C(4)H(12)NO(+)center dot C14H8O4S22-, contains an ethyl(2-hydroxy)aminium cation and half a 2,2'-disulfanediyldibenzoate anion, with the latter disposed about a twofold axis. The cation is a straight chain with the exception of the terminal hydroxy group [the N-C-C-O torsion angle is 66.5 (2)degrees]. A twisted conformation is found for the anion [the C-S-S-C torsion angle is 91.51 (9)degrees and the dihedral angle between the rings is 81.01 (4)degrees]. A supramolecular chain with base vector [101] and a tubular topology is formed in the crystal structure mediated by charge-assisted O-H center dot center dot center dot O- and N+-H center dot center dot center dot O- hydrogen bonding.
Publication Title
Acta Crystallographica Section E: Structure Reports Online
Volume
66
Issue
3
Publisher
International Union of Crystallography
Publisher Location
2 ABBEY SQ, CHESTER, CH1 2HU, ENGLAND