Bis(mu-quinoline-2-carboxylato)-kappa 3 N,O:O;kappa 3 O:N,O-bis[(acetato-kappa 2 O,O')(methanol-kappa O)lead(II)]
Document Type
Article
Publication Date
1-1-2010
Abstract
The dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(CH(3)OH)(2)], lies across an inversion center. The methanol-coordinated PbII atom is chelated by the acetate anion as well as by the quinoline-2-carboxylate anion. One O atom of the quinoline-2-carboxylate anion bridges two symmetry-related PbII atoms, forming the dinuclear compound. Aside from the six atoms connected to the PbII atom by regular coordination bonds, the structure features a long Pb...O interaction [3.145 (3) A] that gives rise to a distorted Psi-square-antiprismatic geometry at the metal center. The H atom of the methanol is hydrogen bonded to an O atom of the acetate.
Publication Title
Acta Crystallographica Section E: Structure Reports Online
Volume
66
Issue
8
Publisher
International Union of Crystallography
Publisher Location
COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA