Bis(mu-2-methyl-8-oxidoquinolin-1-ium-kappa O-2:O)bis[(acetato-kappa O-2,O `)(2-methyl-8-oxidoquinolin-1-ium-kappa O)bis(nitrato-kappa O-2,O `)lanthanum(III)]

Authors

• Y. Fazaeli
• M.M. Amini
• S.W. Ng

Document Type

Article

Publication Date

1-1-2010

Abstract

The N-heterocycles in the centrosymmetric title compound, [La-2(C10H9NO)(4)(CH3COO)(2)(NO3)(4)], exist in the zwitterionic form. One heterocycle binds to a metal center whereas the other bridges two metal centers. Each La atom is chelated by an acetate and two nitrate groups and is surrounded by nine O atoms in a distorted tricapped trigonal-prismatic coordination environment. The N-H groups form intramolecular N-H center dot center dot center dot O hydrogen bonds. One of the nitrate ions is disordered over two positions in a 0.80 (3):0.20 (3) occupancy ratio.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

ISSN

1600-5368

Recommended Citation

Fazaeli, Y.; Amini, M.M.; and Ng, S.W., "Bis(mu-2-methyl-8-oxidoquinolin-1-ium-kappa O-2:O)bis[(acetato-kappa O-2,O `)(2-methyl-8-oxidoquinolin-1-ium-kappa O)bis(nitrato-kappa O-2,O `)lanthanum(III)]" (2010). Research Publications (2006 to 2010). 3167.
https://knova.um.edu.my/research_publications_2006_2010/3167

Volume

66

Issue

2

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA