Bis(3,5-dinitrobenzoato-kappa O-1)tetramethanolcobalt(II)

Document Type

Article

Publication Date

1-1-2010

Abstract

The Co-II atom (site symmetry 1) in the title complex, [Co(C7H3N2O6)(2)(CH3OH)(4)], exists within an octahedral O-6 donor set defined by two O-monodentate 3,5-dinitrobenzoate anions and four methanol O atoms. An intramolecular O-m-H center dot center dot center dot Oc (m = methanol and c = carbonyl) hydrogen bond leads to the formation of an S(6) ring. In the crystal, centrosymmetrically related molecules associate via further O-m-H center dot center dot center dot Oc hydrogen bonds, leading to linear supramolecular chains propagating along the a-axis direction.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

66

Issue

4

Publisher

International Union of Crystallography

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