Bis(2-aminopyrimidine-[kappa]N1)aqua(nitrato-[kappa]O)(nitrato-[kappa]2O,O')zinc(II)
Document Type
Article
Publication Date
1-1-2010
Abstract
The water-coordinated Zn atom in the title monoaqua zinc nitrate adduct of 2-aminopyrimidine, [Zn(NO3)(2)(C4H5N3)(2)-(H2O)], is bonded to a monodentate nitrate ion and is chelated by the other nitrate ion. The heterocyclic ligands coordinate through ring N-donor sites. The coordination geometry about the Zn(II) atom is a distorted octahedron. Intramolecular N-H center dot center dot center dot O hydrogen bonds occur. In the crystal, adjacent adduct molecules are linked by O- H center dot center dot center dot O, O-H center dot center dot center dot N and N-H center dot center dot center dot O hydrogen bonds into a layer motif parallel to ( 001).
Publication Title
Acta Crystallographica Section E: Structure Reports Online
ISSN
1600-5368
Recommended Citation
Gao, S. and Ng, S.W., "Bis(2-aminopyrimidine-[kappa]N1)aqua(nitrato-[kappa]O)(nitrato-[kappa]2O,O')zinc(II)" (2010). Research Publications (2006 to 2010). 3160.
https://knova.um.edu.my/research_publications_2006_2010/3160
Divisions
CHEMISTRY
Volume
66
Issue
10
Publisher
International Union of Crystallography
Publisher Location
COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA