Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix

Authors

• S. Ibrahim
• P.M. Woi
• Y. Alias
• C.J. Pickett

Document Type

Article

Publication Date

1-1-2010

Abstract

We show that a redox active {Fe(4)S(4)}(2+)-cubane assembly covalently bound within a cysteinyl-alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.

Publication Title

Chemical Communications

Recommended Citation

Ibrahim, S.; Woi, P.M.; Alias, Y.; and Pickett, C.J., "Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix" (2010). Research Publications (2006 to 2010). 3119.
https://knova.um.edu.my/research_publications_2006_2010/3119

Volume

46

Issue

43

Publisher

Royal Society of Chemistry

Publisher Location

THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND