Artificial hydrogenases: Assembly of an H-cluster analogue within a functionalised poly(pyrrole) matrix
Document Type
Article
Publication Date
1-1-2010
Abstract
We show that a redox active {Fe(4)S(4)}(2+)-cubane assembly covalently bound within a cysteinyl-alkylammonium functionalised polypyrrole can be modified with a diiron dithiolate carbonyl unit to give an artificial hydrogenase H-cluster framework confined within the polymer matrix.
Publication Title
Chemical Communications
Volume
46
Issue
43
Publisher
Royal Society of Chemistry
Publisher Location
THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
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