8-Hydroxy-2-methylquinolinium diiodido(2-methylquinolin-8-olato-kappa N-2,O)zincate(II) methanol monosolvate

Document Type

Article

Publication Date

1-1-2010

Abstract

The anion of the title salt, (C10H10NO)[Zn(C10H8NO)I-2]center dot-CH3OH, has its metal atom N,O-chelated by the deprotonated 2-methyl-8-hydroxyquinoline ligand. The hydroxy unit of the cation is a hydrogen-bond donor to the alkoxide O atom of the tetrahedrally coordinated anion, whereas the ammonium cation acts as a hydrogen-bond donor to the methanolic O atom. In the crystal, adjacent ion pairs and solvent molecules are linked by a methanol-halogen O-H center dot center dot center dot I hydrogen bond, generating a chain running along the a axis.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

66

Issue

10

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA

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