6,7-Dihydro-5H-1,4-diazepino[1,2,3,4-lmn][1,10]phenanthroline-4,8-di ium tris(thiocyanato-kappa N)cuprate(I)

Document Type

Article

Publication Date

1-1-2010

Abstract

The title copper(I) salt, (C(15)H(14)N(2))[Cu(NCS)(3)], exists as non-interacting cations and trigonal-planar anions. The cation is buckled, the r.m.s. deviation of the atoms passing through the phenanthroline portion being 0.16 angstrom. The Cu(I) atom is displaced by 0.019 (2) angstrom out of the N(3) triangle. The crystal studied was a non-merohedral twin with twin domains in an approximate ratio of 55:45.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

66

Issue

10

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA

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