1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate

Authors

• M. Abu Affan
• D.N.A. Chee
• F.B. Ahmad
• E.R.T. Tiekink

Document Type

Article

Publication Date

1-1-2010

Abstract

In the title compound, C17H18N4O2S center dot H2O, the thiourea derivative is almost planar, with an r.m.s. deviation for the non-H atoms of 0.057 angstrom. The hydroxyl groups lie to the same side of the molecule as the thione S atom, a conformation that allows the formation of intramolecular O-H center dot center dot center dot S and O-H center dot center dot center dot N hydrogen bonds. In the crystal structure, the thiourea and water molecules self-assemble into a two-dimensional array by a combination of O-(water)-H center dot center dot center dot O-hydroxyl, N-H center dot center dot center dot O-water and O-water-H center dot center dot center dot S hydrogen bonds and C-H center dot center dot center dot pi interactions.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

ISSN

1600-5368

Recommended Citation

Abu Affan, M.; Chee, D.N.A.; Ahmad, F.B.; and Tiekink, E.R.T., "1,5-Bis[(E)-1-(2-hydroxyphenyl)ethylidene]thiocarbonohydrazide monohydrate" (2010). Research Publications (2006 to 2010). 2849.
https://knova.um.edu.my/research_publications_2006_2010/2849

Volume

66

Issue

3

Publisher

International Union of Crystallography

Publisher Location

2 ABBEY SQ, CHESTER, CH1 2HU, ENGLAND