1,12-Bis(2-carboxyphenyl)-5,8-dioxa-2,11-diazadodecane-2,11-diium dichloride methanol solvate
Document Type
Article
Publication Date
1-1-2010
Abstract
In the title salt hydrate, C(22)H(30)N(2)O(6)(2+)center dot 2Cl(-)center dot CH(4)O, the dication adopts a U-shaped conformation whereby the benzene rings are splayed out from the chain linking them. All components of the asymmetric unit are linked into a cohesive entity by a combination of O-H center dot center dot center dot Cl(-), N(+)-H center dot center dot center dot Cl(-) and N(+)-H center dot center dot center dot O charge-assisted hydrogen-bonding interactions. The assemblies thus formed are linked into supramolecular helical chains along [010] via C-H center dot center dot center dot O contacts. The resulting chains are, in turn, consolidated into the three-dimensional crystal structure by C-H center dot center dot center dot pi contacts.
Publication Title
Acta Crystallographica Section E: Structure Reports Online
Volume
66
Issue
1
Publisher
International Union of Crystallography
Publisher Location
COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA