1,12-Bis(2-carboxyphenyl)-5,8-dioxa-2,11-diazadodecane-2,11-diium dichloride methanol solvate
Document Type
Article
Publication Date
1-1-2010
Abstract
In the title salt hydrate, C(22)H(30)N(2)O(6)(2+)center dot 2Cl(-)center dot CH(4)O, the dication adopts a U-shaped conformation whereby the benzene rings are splayed out from the chain linking them. All components of the asymmetric unit are linked into a cohesive entity by a combination of O-H center dot center dot center dot Cl(-), N(+)-H center dot center dot center dot Cl(-) and N(+)-H center dot center dot center dot O charge-assisted hydrogen-bonding interactions. The assemblies thus formed are linked into supramolecular helical chains along [010] via C-H center dot center dot center dot O contacts. The resulting chains are, in turn, consolidated into the three-dimensional crystal structure by C-H center dot center dot center dot pi contacts.
Publication Title
Acta Crystallographica Section E: Structure Reports Online
ISSN
1600-5368
Recommended Citation
Johnson, S.; Musie, G.T.; and Tiekink, E.R.T., "1,12-Bis(2-carboxyphenyl)-5,8-dioxa-2,11-diazadodecane-2,11-diium dichloride methanol solvate" (2010). Research Publications (2006 to 2010). 2841.
https://knova.um.edu.my/research_publications_2006_2010/2841
Volume
66
Issue
1
Publisher
International Union of Crystallography
Publisher Location
COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA