[2,6-Bis(6-methylquinolin-2-yl)pyridine-kappa N-3,N `,N `']dichloridomanganese(II)

Document Type

Article

Publication Date

1-1-2010

Abstract

In the molecule of the title compound, [MnCl2(C25H19N3)], the three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Mn-II atom is 34% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). One of the Cl atoms is disordered over two positions in a 0.82 (3):0.18 (3) ratio. Weak intermolecular C-H center dot center dot center dot Cl hydrogen bonding occurs in the crystal structure.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

66

Issue

10

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA

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