(N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV)

Authors

• N. Awang
• I. Baba
• B.M. Yamin
• S.W. Ng
• E.R.T. Tiekink

Document Type

Article

Publication Date

1-1-2010

Abstract

The Sn atom in the title compound, [Sn(C6H5)(3)(C8H16NS2)], is pentacoordinated by two S atoms, derived from an asymmetrically coordinating dithiocarbamate ligand, and three ipso-C atoms. The coordination geometry is intermediate between square-pyramidal and trigonal-bipyramidal, with a leaning towards the latter. The presence of close intramolecular C-H center dot center dot center dot S contacts preclude the S atoms from forming significant intermolecular interactions. Rather, molecules are consolidated in the crystal structure by C-H center dot center dot center dot pi interactions.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

ISSN

1600-5368

Recommended Citation

Awang, N.; Baba, I.; Yamin, B.M.; Ng, S.W.; and Tiekink, E.R.T., "(N-sec-Butyl-N-n-propyldithiocarbamato-kappa S-2,S `)triphenyltin(IV)" (2010). Research Publications (2006 to 2010). 2802.
https://knova.um.edu.my/research_publications_2006_2010/2802

Volume

66

Issue

9

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA