(Acetylacetone 3-hydroxy-2-naphthoylhydrazonato-kappa 3 O,N',O')(methoxo-kappa O)oxidovanadate(V)

Authors

H.W. Wong
K.M. Lo
S.W. Ng

Document Type

Article

Publication Date

1-1-2010

Abstract

The tridentate Schiff base ligand in the title compound, [V(C(16)H(14)N(2)O(3))(CH(3)O)O], has its O, N and O' atoms spanning three basal positions of the square-based-pyrimidally VV atom. The fourth basal site is occupied by a methoxo ligand, which results from a deprotonated methanol solvent molecule, and the oxido ligand occupies the apical position. The hydroxy H atom forms an intramolecular O-H...N hydrogen bond with an N-atom acceptor site.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

66

Issue

8

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA