(5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate
Document Type
Article
Publication Date
1-1-2010
Abstract
The Co-II atom in the title compound, [Co(C8H5NO4)(C12H8N2)(H2O)(3)]center dot 3H(2)O, is six-coordinated in a CoN3O3 octahedral geometry; the water-coordinated Co-II atom is chelated by the N-heterocycle. An intermolecular N-H center dot center dot center dot O hydrogen bond occurs. The carboxylate entity coordinates through the amino group. The carboxylate donor unit, coordinated and uncoordinated water molecules interact through O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds, generating a tightly-held three-dimensional cage-like network.
Publication Title
Acta Crystallographica Section E: Structure Reports Online
ISSN
1600-5368
Recommended Citation
Zhang, Kou-Lin; Diao, Guo-Wang; and Ng, S.W., "(5-Aminoisophthalato-kappa N)triaqua(1,10-phenanthroline-kappa N-2,N `)cobalt(II) trihydrate" (2010). Research Publications (2006 to 2010). 2784.
https://knova.um.edu.my/research_publications_2006_2010/2784
Volume
66
Issue
11
Publisher
International Union of Crystallography
Publisher Location
COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA