(4-Chlorobenzohydrazidato-kappa N-2 `,O)[2-(4-chlorobenzoylhydrazinylidene-kappa N-2(1),O)-3-phenylpropionato(2-)-kappa O-1]oxidovanadium(V) methanol monosolvate

Authors

• H.W. Wong
• K.M. Lo
• S.W. Ng

Document Type

Article

Publication Date

1-1-2010

Abstract

The V-V atom in the title compound, [V(C7H6ClN2O)(C16H11ClN2O3)O]center dot CH3OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O'-chelated by the (benzoylhydrazinylidene) propionate dianion. The distorted octahedral trans-N2O4 coordination geometry is completed by the vanadyl O atom. The mononuclear and solvent molecules are linked by N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds about a center of inversion, generating a dimer.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

ISSN

1600-5368

Recommended Citation

Wong, H.W.; Lo, K.M.; and Ng, S.W., "(4-Chlorobenzohydrazidato-kappa N-2 `,O)[2-(4-chlorobenzoylhydrazinylidene-kappa N-2(1),O)-3-phenylpropionato(2-)-kappa O-1]oxidovanadium(V) methanol monosolvate" (2010). Research Publications (2006 to 2010). 2783.
https://knova.um.edu.my/research_publications_2006_2010/2783

Volume

66

Issue

12

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA