(2-Carboxyacetato-kappa O-2(1),O-1 `)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-kappa N-4,N `,N `',N `'')nickel(II) perchlorate acetonitrile solvate

Document Type

Article

Publication Date

1-1-2010

Abstract

In the crystal structure of the title salt, [Ni(C3H3O4)-(C16H36N4)]ClO4 center dot CH3CN, the macrocycle folds around the Ni-II atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N-H center dot center dot center dot O hydrogen bonds into centrosymmetric dimers. Further N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds link the complex molecules and the perchlorate ions.

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

66

Issue

11

Publisher

International Union of Crystallography

Publisher Location

COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA

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