Bis(mu-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-kappa O-4(2),N-1,S:O-2;kappa O-4(2):O-2,N-1,S-bis chloridozinc(II) dimethyl sulfoxide trisolvate

Authors

Kong Wai TanFollow
S.W. Ng
Mohd Jamil MaahFollow
C.H. Ng

Document Type

Article

Publication Date

1-1-2009

Abstract

The two Zn-II atoms in the title compound, [Zn-2(C10H12N3O2S)(2)Cl-2]center dot 3C(2)H(6)OS, are each N,O,S-chelated by a mono-deprotonated Schiff base ligand. The Zn atoms are bridged through the phenolate O atom, leading to a central Zn2O2 core. Each Zn atom has a Cl atom in the apical position of a distorted square-pyramidal environment. Hydroxy-DMSO (DMSO is dimethyl sulfoxide) O-H center dot center dot center dot O and amide-DMSO N-H center dot center dot center dot O hydrogen bonds link the components of the crystal structure. Two of the DMSO molecules are partially disordered, with each modelled over two sites of equal weight.

Divisions

CHEMISTRY

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

65

Publisher

International Union of Crystallography

Additional Information

Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA