Document Type
Article
Publication Date
1-1-2009
Abstract
The two Zn-II atoms in the title compound, [Zn-2(C10H12N3O2S)(2)Cl-2]center dot 3C(2)H(6)OS, are each N,O,S-chelated by a mono-deprotonated Schiff base ligand. The Zn atoms are bridged through the phenolate O atom, leading to a central Zn2O2 core. Each Zn atom has a Cl atom in the apical position of a distorted square-pyramidal environment. Hydroxy-DMSO (DMSO is dimethyl sulfoxide) O-H center dot center dot center dot O and amide-DMSO N-H center dot center dot center dot O hydrogen bonds link the components of the crystal structure. Two of the DMSO molecules are partially disordered, with each modelled over two sites of equal weight.
Publication Title
Acta Crystallographica Section E: Structure Reports Online
ISSN
1600-5368
Recommended Citation
Tan, Kong Wai; Ng, S.W.; Maah, Mohd Jamil; and Ng, C.H., "Bis(mu-4-hydroxy-2-oxidobenzaldehyde 4-ethylthiosemicarbazone)-kappa O-4(2),N-1,S:O-2;kappa O-4(2):O-2,N-1,S-bis chloridozinc(II) dimethyl sulfoxide trisolvate" (2009). Research Publications (2006 to 2010). 2276.
https://knova.um.edu.my/research_publications_2006_2010/2276
Divisions
CHEMISTRY
Volume
65
Publisher
International Union of Crystallography
Additional Information
Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA