(4-Hydroxy-2-oxidobenzaldehyde thiosemicarbazonato-kappa O-3(2),N-1,S)(1, 10-phenanthroline-kappa N-2,N ')zinc(II) dimethyl sulfoxide disolvate monohydrate

Authors

Kong Wai TanFollow
S.W. Ng
Mohd Jamil MaahFollow
C.H. Ng

Document Type

Article

Publication Date

1-1-2009

Abstract

The Zn-II atom in the title compound, [Zn(C8H7N3O2S)-(C12H8N2)]center dot 2C(2)H(6)OS center dot H2O, is N,N '-chelated by the N-heterocycle and N, O, S-chelated by the deprotonated Schiff base in a distorted square-pyramidal enviroment. Hydrogen bonds link the mononuclear molecule, the water and the dimethyl sulfoxide (DMSO) molecules into a linear chain motif. One DMSO molecule is disordered over two positions in respect of the S atom in an approximate 1:1 ratio.

Divisions

CHEMISTRY

Publication Title

Acta Crystallographica Section E: Structure Reports Online

Volume

65

Publisher

International Union of Crystallography

Additional Information

Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA