Tris[2,5-bis(1H-benzimidazol-2-yl)pyridinato-κ2 N 1,N 2]cobalt(III) dihydrate
Document Type
Article
Publication Date
1-1-2006
Abstract
In the title compound, [Co(C19H12N5) 3]·2H2O, three mono-deprotonated 2,5-bis(benzimidazolyl)pyridine heterocycles chelate to cobalt(III) through the N atom of one benzimidazolyl arm of the heterocycle as well as through the pyridyl N atom to form a fairly regular six-coordinate, octahedral geometry geometry for cobalt. A network of N-H⋯N, N H⋯O and O -H⋯N hydrogen bonds involving the non-coordinated water molecules results in a layered structure. © 2006 International Union of Crystallography All rights reserved.
Keywords
Cobalt, Oxygenation, 4-Toluic Acid
Divisions
CHEMISTRY
Publication Title
Acta Crystallographica Section E: Structure Reports Online
Volume
62
Issue
4
Publisher
International Union of Crystallography
COinS