Document Type
Article
Publication Date
1-1-2008
Abstract
In the title compound, [Ni(C(17)H(14)N(3)S(2))(2)]center dot 2C(3)H(7)NO, the Ni atom (site symmetry (1) over bar) is N,S-chelated by two deprotonated Schiff base anions in a distorted square-planar geometry. The dihedral angle between the aromatic ring planes within the ligand is 86.37 (13)degrees. In the crystal structure, an N-H center dot center dot center dot O hydrogen bond links the complex to the dimethylformamide solvent molecule.
Keywords
Schiff-Base Ligand, Crystal-Structure, Nickel(Ii) Complex, Metal-Complexes
Divisions
CHEMISTRY
Publication Title
Acta Crystallographica Section E: Structure Reports Online
Volume
64
Publisher
International Union of Crystallography
Additional Information
Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA
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