{4-Chloro-2′-[1-(5-chloro-2-oxidophenyl)-ethylidene- κ3O,N2′ ,O′]benzhydrazido}-tris(pyridine- κN)nickel(II) pyridine solvate
Document Type
Article
Publication Date
1-1-2004
Abstract
The crystal structure of the title compound, [Ni(C15H 10Cl2-N2O2)(C5H 5N)3]·C5H5N, is built of molecules of a mononuclear nickel complex and uncoordinated solvent pyridine molecules. The NiII atom in the complex is coordinated by two O and one N atoms of the meridional tridentate ligand, viz. the twice deprotonated hydrazone formed from 2-hydroxy-5-chloroacetophenone and p-chlorobenzhydrazide. The remaining three coordination sites of the Ni octahedron are occupied by three coordinated pyridine ligands. © 2004 International Union of Crystallography Prinled in Great Britain - all rights reserved.
Keywords
Benzene, Carrier concentration, Chemical bonds, Complexation, Coordination reactions, Crystal structure, Crystallization, Ethanol, Filtration, Hydrazine, Molecular structure, Organometallics, 2-hydroxyacetophenone, Benzhydrazide moiety, Octahedral coordination, Pyridine ligands, Nickel compounds
Divisions
CHEMISTRY
Publication Title
Acta Crystallographica Section E: Structure Reports Online
Volume
60
Issue
9
Publisher
International Union of Crystallography
Additional Information
Department of Chemistry, Faculty of Science Building, University of Malaya, 50603 Kuala Lumpur, MALAYSIA