catena-Poly[[bis(μ-1,10-phenanthrolin-2-olato-κ3N,N′:O)dicopper(I,II)(Cu—Cu)]-μ-chlorocopper(I)-μ-chloro]
Document Type
Article
Publication Date
1-1-2005
Abstract
In the crystal structure of the title compound, [Cu3(C 12H7N2O)2Cl2] n, the mixed-valence CuI/CuII cation and the cuprate(I) anion both lie on centres of inversion. The O atom of one half of the planar N,N′-chelated dinuclear copper cation binds to the Cu atom of the other half; the geometry around the metal atom is square-planar, owing to the symmetry-related metal atom at a distance of 2.3945 (5) Å. The dinuclear cations are bridged through the anions to form an infinite linear chain. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved.
Keywords
Tautomers, Dione, Ligands
Divisions
CHEMISTRY
Publication Title
Acta Crystallographica Section E: Structure Reports Online
Volume
61
Issue
6
Publisher
International Union of Crystallography
COinS